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Convenient peripheral aroyloxylation reactions of porphyrins and chlorophyll-a-based chlorins with benzoyl peroxide |
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| Authors: | Jiazhu Li Peng Zhang Nan-Nan Yao Li-Li Zhao Jin-Jun Wang Young Key Shim |
| Institution: | 1. College of Chemistry and Chemical Engineering, Yantai University, Yantai 264005, China;2. Shandong Applied Research Centre of Gold Nanotechnology (Au-SDARC), Yantai 264005, China;3. PDT Research Institute, School of Nano System Engineering, Inje University, Gimhae 621-749, Republic of Korea |
| Abstract: | A practical and efficient methodology for the formation of C–O bonds on the porphyrin/chlorin periphery was developed. The aroyloxy-substituted porphyrins and chlorins related to chlorophyll-a at the β- and meso-positions, respectively, were conveniently synthesized by the free radical substitution reaction with benzoyl peroxide and its homologs. |
| Keywords: | Aroyloxylation Porphyrin Chlorin Benzoyl peroxide |
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