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Enantiodifferentiating [2+2] photocycloaddition of cyclohexenone carboxylic acid with ethylene using 8-phenylmenthyl amine as a chiral template |
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| Authors: | Yuuki Yanagisawa Yasuhiro NishiyamaHiroki Tanimoto Tsumoru MorimotoKiyomi Kakiuchi |
| Institution: | Graduate School of Materials Science, Nara Institute of Science and Technology (NAIST), 8916-5 Takayama, Ikoma, Nara 630-0101, Japan |
| Abstract: | Enantiodifferentiating 2+2] photocycloaddition of cyclohexenone carboxylic acid with the smallest olefin, ethylene, was accomplished using 8-phenylmenthyl amine as a chiral template. Particularly, we succeeded in enhancing the enantiomeric excess (ee) value by selective excitation of a chiral substrate–template supramolecular complex. |
| Keywords: | [2+2] Photocycloaddition Enantiodifferentiating Chiral template Ethylene Cyclobutane |
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