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Oxidative kinetic resolution of racemic alkyl aryl carbinols by an electronically tuned chiral nitroxyl radical |
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| Authors: | Shohei Hamada Yoshiyuki WadaTakahiro Sasamori Norihiro TokitohTakumi Furura Takeo Kawabata |
| Institution: | Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011, Japan |
| Abstract: | A method for oxidative kinetic resolution of racemic alcohols catalyzed by chiral nitroxyl radical (R,R)-1 has been developed. This method is especially effective for the kinetic resolution of tert-butyl aryl carbinols (s = up to 23). |
| Keywords: | Nitroxyl radical Oxidation Kinetic resolution Alcohols Hydride shift |
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