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A highly efficient and recyclable silica-supported palladium catalyst for alcohol oxidation reaction
Authors:Debojeet Sahu  Chandan Sarmah  Pankaj Das
Affiliation:1. Department of Chemistry, Dibrugarh University, Dibrugarh 786004, Assam, India;2. Department of Chemistry, Rajiv Gandhi University, Doimukh, Rono Hills, Itanagar 791112, Arunachal Pradesh, India
Abstract:A silica supported palladium catalyst (SiO2@APTES-Pd) showed excellent activity and reusability for selective oxidation of alcohols to corresponding carbonyl compounds with H2O2 as oxidant under base free environment. A wide range of alcohols including aliphatic alcohols are tolerated as substrates with a low loading of palladium (0.1 mol %).
Keywords:Heterogeneous catalyst   Palladium   Alcohol oxidation   Silica support   Hydrogen peroxide
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