Simple and catalyst-free method for the synthesis of diaryl selenides by reactions of arylselenols and arenediazonium salts |
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Authors: | Renata A Balaguez Vanessa Gentil RicordiCamilo S Freitas Gelson PerinRicardo F Schumacher Diego Alves |
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Institution: | Laboratório de Síntese Orgânica Limpa, LASOL, CCQFA, Universidade Federal de Pelotas, UFPel, P.O. Box 354, 96010-900 Pelotas, RS, Brazil |
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Abstract: | We describe here a simple and catalyst-free method to synthesize diaryl selenides by reaction of arenediazonium tetrafluoroborate salts with arylselenols, generated in situ by using diaryl diselenides and hypophosphorous acid (H3PO2), using THF as solvent. This is a direct nucleophilic aromatic substitution (SNAr) reaction performed with diaryl diselenides and arenediazonium salts bearing electron-withdrawing and electron-donating groups affording the corresponding diaryl selenides in moderated to good yields. |
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Keywords: | Organoselenium compounds Selenol Arenediazonium salts Hypophosphorous acid Nucleophilic aromatic substitution |
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