Self-assembly of a thymine quartet and quadruplex via an organic template |
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| Authors: | Wei-Qiang Benjamin Hui John C. Sherman |
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| Affiliation: | University of British Columbia, 2036 Main Mall, Vancouver V6T 1Z1, Canada |
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| Abstract: | The synthesis of two hydrophobic cavitands bearing four (1) and eight (2) thymidine residues covalently linked with triazole moieties is reported. Spectral evidence indicates the adoption of a hydrogen-bonded T-quartet assembly by 1 in chloroform at low temperature and a π-stacked quadruplex by 2 in DMSO under ambient conditions. |
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| Keywords: | Cavitands Supramolecular chemistry Template synthesis Thymine quartet Thymine quadruplex |
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