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Development of chemoselective photoreduction of nitro compounds under solar light and blue LED irradiation
Authors:Zahra Zand  Foad Kazemi  Saber Hosseini
Institution:1. Department of Chemistry, Institute for Advanced Studies in Basic Sciences (IASBS), 49195-1159 Zanjan, Iran;2. Center for Climate and Global Warming (CCGW), Institute for Advanced Studies in Basic Sciences (IASBS), Gava Zang, Zanjan, Iran
Abstract:Solar light and blue light irradiation of the commercially available heterogeneous nano photocatalyst TiO2–P25 leads to reduction of nitro compounds to give the corresponding amines. The methodology provides a green and mild approach to this useful class of organic compounds. Aromatic nitro compounds containing a wide range of functional groups tolerated the conditions to give, chemoselectively the corresponding amines in excellent yields.
Keywords:Photocatalysis  LED  TiO2&ndash  P25  Solar light  Nitro compound
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