One pot direct synthesis of β-ketoesters via carbonylation of aryl halides using cobalt carbonyl |
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| Authors: | Poongavanam Baburajan Kuppanagounder P Elango |
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| Institution: | Department of Chemistry, Gandhigram Rural Institute (Deemed University), Gandhigram 624302, India |
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| Abstract: | A direct method for the synthesis of β-ketoesters from aryl halides (iodide, bromide) has been described by using cobalt carbonyl as carbon monoxide source in microwave irradiation. Using this protocol, a wide variety of substituted aryl halides has been successfully converted to corresponding β-ketoesters. |
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| Keywords: | Aryl halides Carbonylation β-Ketoesters Imidazole Co2(CO)8 |
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