Synthesis,physical properties,and structure of TIPS-difuranoacenes |
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Authors: | Motonori Watanabe Ching-Ting Chien Yan-Duo Lin Yuan Jay Chang Yuh-Sheng Wen Kenta Goto Masahiko Shibahara Teruo Shinmyozu Tahsin J. Chow |
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Affiliation: | 1. International Institute for Carbon-Neutral Energy Research (I2CNER), Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan;2. Institute of Chemistry, Academia Sinica, Taipei 115, Taiwan;3. Department of Chemistry, Tung Hai University, Taichung 407, Taiwan;4. Institute for Materials Chemistry and Engineering (IMCE), Kyushu University, 6-10-1 Hakozaki, Fukuoka 812-8581, Japan;5. Department of Chemistry, Faculty of Education and Welfare Science, Oita University, 700 Dannoharu, Oita 870-1192, Japan |
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Abstract: | The synthesis, physical properties, and structure of triisopropylsilylethynyltetracenodifuran (2) and pentacenodifuran (3) derivatives were reported. There showed high stability in solution in the dark, yet decomposed under light. Single crystal of pentacenodifuran was analyzed by X-ray diffraction analysis, and showed one dimensional packing array along the c-axis. The molecules were stacked with a 3.30 Å interlayer distance. The crystals exhibited a high thermal stability under an ambient condition. |
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Keywords: | Pentacene Hexacene Heptacene Oligoacene |
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