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Metal-free synthesis of aryl esters by coupling aryl carboxylic acids and aryl boronic acids
Authors:Jayaraman Sembian Ruso  Nagappan Rajendiran  Rajendran Senthil Kumaran
Affiliation:1. Department of Polymer Science, Maramalai Campus, University of Madras, Guindy, Chennai 600025, India;2. Syngene International Ltd, Biocon Park #2 and 3, Bommasandra, Jigani Link Road, Bangalore 560099, India
Abstract:A facile synthesis of aryl esters is developed by coupling aryl carboxylic acids and aryl boronic acids in the presence of PhI(OAc)2 and carbonyl diimidazole. A wide range of functional groups were tolerant to the metal-free reaction condition that led to the desired products in good yields.
Keywords:Aryl ester   Aryl boronic acid   Phenyl iododiacetate   Carbonyl diimidazole
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