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ZnCl2 promoted efficient,one-pot synthesis of 3-arylmethyl and diarylmethyl indoles |
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| Authors: | Selva Ganesan Subramaniapillai Asaithampi Ganesan |
| Institution: | School of Chemical and Biotechnology, SASTRA University, Thanjavur 613401, India |
| Abstract: | Anhydrous ZnCl2 mediated convenient, one-pot synthesis of 3-arylmethyl and diarylmethyl indoles was accomplished in good yields. Under reaction condition, in situ formation of kinetically stable bis(indolyl)methane product was identified. Its subsequent conversion to the thermodynamically stable 3-diarylmethyl indole at elevated temperature and pressure was confirmed by carrying out pressure tube reaction with bis(indolyl)methane. |
| Keywords: | KWOGMHUUISUZSZ-UHFFFAOYSA-N XBVWFPKRKZWSCO-UHFFFAOYSA-N QDGMLQLWBDSMMF-UHFFFAOYSA-N GFKZKSAIJJMVBM-UHFFFAOYSA-N OSQUSJYBZXDYMA-UHFFFAOYSA-N OVJWCGBEMVSHEE-UHFFFAOYSA-N RCYLMWKLJYFDAF-UHFFFAOYSA-N KHJMHGYEOLDHHT-UHFFFAOYSA-N |
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