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Tuning of the properties of rhodopsin-based molecular switches
Authors:Marina Blanco-Lomas  David Martínez-LópezPedro J Campos  Diego Sampedro
Institution:Departamento de Química, Centro de Investigación en Síntesis Química (CISQ), Universidad de La Rioja, Madre de Dios 51, 26006 Logroño, La Rioja, Spain
Abstract:The modification of relevant chemical properties of rhodopsin-based molecular photoswitches is presented. We show how both the substituents present and the nitrogen atom quaternization are capable to change the wavelength of absorption and the thermal stability of the photoisomer. Adjusting these properties, the molecular switches could be turned into useful compounds for solar energy storage devices.
Keywords:Photoswitches  Molecular devices  Solar energy storage  Photochemistry  Photophysics
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