Lipase catalyzed Cannizzaro-type reaction with substituted benzaldehydes in water |
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| Authors: | Benu Arora Pramod S. Pandey Munishwar N. Gupta |
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| Affiliation: | 1. Chemistry Department, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110016, India;2. Department of Biochemical Engineering and Biotechnology, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110016, India |
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| Abstract: | Lipases were found to catalyze Cannizzaro-type reaction of substituted benzaldehydes in aqueous medium at 30 °C without the addition of any external redox reagent. The ratio of alcohol product to acid product varied with nature of the substituted benzaldehyde, enzyme, and the presence of organic co-solvent. |
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| Keywords: | Cannizzaro reaction Catalytic promiscuity Novozyme 435 Organic reaction in aqueous media |
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