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Phosphoric acid mediated tautomerism of imines: addition of a secondary enamine intermediate to aldehydes |
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| Authors: | Lindsey O. Davis Marcella A. PutriCaitlin L. Meyer Christopher P. Durant |
| Affiliation: | Department of Chemistry, Berry College, PO Box 495016, Mount Berry, GA 30149, United States |
| Abstract: | A phosphoric acid derivative has been shown to promote the addition between an imine and several aldehyde substrates through an enamine intermediate to give cross-aldol condensation products. The reaction scope and preliminary mechanistic investigations will be presented. |
| Keywords: | Organocatalysis Aldol condensation Aza-ene reaction Phosphoric acid |
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