Synthesis and photochromism of novel unsymmetrical diarylethenes with an azaindole unit |
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Authors: | Zhiyuan Sun Hui LiShouzhi Pu Gang LiuBing Chen |
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Affiliation: | Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, Nanchang, Jiangxi 330013, PR China |
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Abstract: | A new class of unsymmetrical photochromic diarylethenes with an azaindole moiety has been firstly synthesized. Their properties, including photochromism, crystal structure, as well as fluorescence, were investigated systematically. The azaindole was connected directly to the central cyclopentene ring as a heteroaryl moiety and available to participate in the photoisomerization reaction. Each of the diarylethenes exhibited favorable photochromism, good thermal stability, remarkable fatigue resistance, and notable fluorescence switches in both solution and solid media. The substituents at the para-position of the terminal benzene ring affected evidently their properties: the electron-donating methoxy could be effective to enhance the cyclization quantum yield, while the electron-withdrawing cyano could shift the absorption maximum to a longer wavelength in both hexane and solid film. The results revealed that the introduction of azaindole moieties and different substituents played an important role in the photoisomerization process of these diarylethenes. |
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Keywords: | Photochromism Diarylethene Azaindole moiety Substituent effect |
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