A facile flow-through phosphorimetric sensing device for simultaneous determination of naptalam and its metabolite 1-naphthylamine |
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Authors: | A. Salinas-Castillo,A. Segura-Carretero,A. Ferná ndez-Gutié rrez |
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Affiliation: | a Department of Analytical Chemistry, Faculty of Sciences, University of Granada, C/Fuentenueva s/n, E-18071 Granada, Spain b Center for Chemical Sensors, Swiss Federal Institute of Technology Zurich (ETHZ), Technoparkstrasse 1, CH-8005 Zürich, Switzerland |
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Abstract: | This paper presents the development of a single flow-through phosphorescence optosensor for simultaneous determination of pesticide N-1-naphthylphthlamic acid (NAP) and its metabolite 1-naphthylamine (NNA). The system works as a simple and rapid phosphorimetry-biparameter sensor. It is based in the on-line immobilization of the analytes onto a non-ionic resin solid support (Amberlite XAD 7) in a continuous flow system, followed by the measurement of their native phosphorescence. The determination was performed using 0.2 M TlNO3 and 15 mM Na2SO3 in a carrier flow. The developed sensor was satisfactorily applied to the determination of these pesticides in drinking and mineral waters (recovery percentages between 82.8 and 114.1% with inferior relative standard deviations to 3.1%). |
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Keywords: | Phosphorescence Optical sensor Flow injection Pesticide Naptalam 1-Naphthylamine Water |
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