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Mesoporous Bubble‐like Manganese Silicate as a Versatile Platform for Design and Synthesis of Nanostructured Catalysts
Authors:Guowu Zhan  Christopher C Yec  Prof Dr Hua Chun Zeng
Institution:NUS Graduate School for Integrative Sciences and Engineering and Department of Chemical and Biomolecular Engineering, Faculty of Engineering, National University of Singapore, 10 Kent Ridge Crescent, Singapore 119260
Abstract:Manganese silicate in bubble‐like morphology was used as a versatile platform to prepare a new class of yolk–shell hybrids. The mesoporosity of the shell was generated from the interbubble space and the bubble structure of manganese silica was used to hold and support nanoparticles (e.g., Au, Ag, Pt, Co, Ni, Au–Pd alloy, MoO2, Fe3O4, carbon nanotubes and their combinations). We also used heterogeneous catalysis reactions to demonstrate the workability of these catalysts in both liquid and gas phases.
Keywords:CO2 hydrogenation  heterogeneous catalysis  hollow structures  manganese silicate  mesoporous materials
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