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Unprecedented Trinuclear AgI Complex with 2,4,6‐Tris(2‐pyrimidyl)‐1,3,5‐triazine as an Efficient Catalyst for the Aziridination of Olefins
Authors:Dr. Damir A. Safin  Dr. Amélie Pialat  Dr. Ilia Korobkov  Prof. Muralee Murugesu
Affiliation:Department of Chemistry, University of Ottawa, 10 Marie Curie Private, K1N 6N5 Ottawa, ON (Canada)
Abstract:An unprecedented trinuclear heteroleptic AgI complex was isolated using a stable multidentate 2,4,6‐tris(2‐pyrimidyl)‐1,3,5‐triazine (TPymT) ligand. The obtained compound is an efficient catalyst for the direct aziridination of terminal olefins.
Keywords:aziridination  catalysis  crystal structure  olefins  silver cluster
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