Unprecedented Trinuclear AgI Complex with 2,4,6‐Tris(2‐pyrimidyl)‐1,3,5‐triazine as an Efficient Catalyst for the Aziridination of Olefins |
| |
| Authors: | Dr. Damir A. Safin Dr. Amélie Pialat Dr. Ilia Korobkov Prof. Muralee Murugesu |
| |
| Affiliation: | Department of Chemistry, University of Ottawa, 10 Marie Curie Private, K1N 6N5 Ottawa, ON (Canada) |
| |
| Abstract: | An unprecedented trinuclear heteroleptic AgI complex was isolated using a stable multidentate 2,4,6‐tris(2‐pyrimidyl)‐1,3,5‐triazine (TPymT) ligand. The obtained compound is an efficient catalyst for the direct aziridination of terminal olefins. |
| |
| Keywords: | aziridination catalysis crystal structure olefins silver cluster |
|
|
