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Unilamellar Vesicles from Amphiphilic Graphene Quantum Dots
Authors:Sukhendu Nandi  Sofiya Kolusheva  Ravit Malishev  Alexander Trachtenberg  T P Vinod  Raz Jelinek
Institution:1. Department of Chemistry, Ben Gurion University of the Negev, Beer Sheva 84105 (Israel), Fax: (+972)?8‐6472943;2. Ilse Katz Institute for Nanoscale Science & Technology, Ben Gurion University of the Negev, Beer Sheva 84105 (Israel)
Abstract:Graphene quantum dots (GQDs) have attracted considerable interest due to their unique physicochemical properties and various applications. For the first time it is shown that GQDs surface‐functionalized with hydrocarbon chains (i.e., amphiphilic GQDs) self‐assemble into unilamellar spherical vesicles in aqueous solution. The amphiphilic GQD vesicles exhibit multicolor luminescence that can be readily exploited for membrane studies by fluorescence spectroscopy and microscopy. The GQD vesicles were used for microscopic analysis of membrane interactions and disruption by the peptide beta‐amyloid.
Keywords:amphiphiles  graphene  membranes  quantum dots  vesicles
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