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电化学法改性阳极对MFC性能的影响
引用本文:电化学法改性阳极对MFC性能的影响.电化学法改性阳极对MFC性能的影响[J].燃料化学学报,2016,44(5):628-633.
作者姓名:电化学法改性阳极对MFC性能的影响
作者单位:College of Environment and Safety Engineering, Shenyang University of Chemical Technology, Shenyang 110142, China
基金项目:国家自然科学基金(61143007)和沈阳市科学技术计划(F14-207-600)项目资助
摘    要:采用不同质量分数的NH_4NO_3和(NH_4)_2S_2O_8溶液作为电解液,对双室微生物燃料电池的阳极炭布进行改性。以餐厨废水作为阳极底物,以K_3Fe(CN)_6]和NaCl混合溶液为阴极液,考察不同电解液改性阳极条件下微生物燃料电池的产电性能及污水处理效果。结果表明,采用NH_4NO_3或(NH_4)_2S_2O_8改性炭布作为阳极的微生物燃料电池的发电性能和水处理效果均有改善。其中,采用质量分数为4%的(NH_4)_2S_2O_8溶液作为阳极改性电解液时,微生物燃料电池系统的产电性能达到最佳,其稳态电流密度约为60 m A/m~2,COD去除率约为42.5%。

关 键 词:微生物燃料电池(MFC)  电化学改性  阳极  餐厨废水  
收稿时间:2015-09-01

Effect of electrochemically modified anode on the performance of MFC
FAN Li-ping,XU Dan-dan.Effect of electrochemically modified anode on the performance of MFC[J].Journal of Fuel Chemistry and Technology,2016,44(5):628-633.
Authors:FAN Li-ping  XU Dan-dan
Abstract:NH4NO3 and (NH4)2S2O8 with different mass fractions were used as electrolyte to modify the anodic carbon cloth used in a double chamber microbial fuel cell. Using some restaurant wastewater as the anode substrate and the mixed solution of K3Fe(CN)6] and NaCl as catholyte, the power generation performance and wastewater treatment effect of a microbial fuel cell with modified anode by different electrolytes were studied. The experimental results show that the microbial fuel cell with modified anode by NH4NO3 and (NH4)2S2O8 has a better power generation performance and sewage treatment effect. The power generating ability and the purifying effect of the microbial fuel cell achieve the optimal state with the steady current density of about 60 mA/m2 and the removal rate of COD of about 42.5% when the (NH4)2S2O8 of 4% mass fraction is used as the modified electrolyte of anode.
Keywords:microbial fuel cell  electrochemical modification  anode  restaurant wastewater  
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