Enthalpies and heat capacities of hematoporphyrin solutions in N,N-dimethylformamide and octanol-1 |
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Authors: | A V Kustov N L Smirnova and M B Berezin |
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Abstract: | Heat effects of the dissolution of hematoporphyrin tetramethyl ether are measured on a variable-temperature calorimeter for
the first time in N,N-dimethylformamide and octanol-1 in the temperature range of 298 to 318 K. Standard enthalpies and heat
capacities of dissolution of bioligand are calculated and compared to data obtained earlier for deuteroporphyrin dimethyl
ether and ethyl acetate. Partial molar heat capacities of hematoporhyrin are determined at infinite dilution using data from
differential scanning calorimetry. |
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