On the interfacial chemistry of aryl diazonium compounds in polymer science |
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Authors: | Zakaria Salmi Sarra Gam-Derouich Samia Mahouche-Chergui Mireille Turmine Mohamed M. Chehimi |
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Affiliation: | 1.ITODYS, UMR CNRS 7086,University of Paris Diderot, Sorbonne Paris Cité,Paris Cedex 13,France;2.LISE, CNRS (UPR 15) and University Pierre and Marie Curie, Case 133,Paris,France |
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Abstract: | This review emphasises the role of aryl diazonium compounds as a new class of coupling agents for grafting polymer thin layers onto carbon, diamond, metals, metal oxides, alloys, semi-conductors, ceramics, and polymers. Physical and chemical methods are first reported for anchoring aryl layers to the surfaces, then the review concentrates on the modification of the above substrates by thin polymer films via a range of the “grafting from” and “grafting onto” strategies. Some applications are described which highlight the important role that diazonium salts will continue to play in the near future in the polymer and surface sciences. |
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