New synthetic approach to phenylmethanesulfonamide derivatives on the basis of phenyl-N-(2,2,2-trichloroethylidene)-methanesulfonamide |
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| Authors: | Yu. A. Aizina G. G. Levkovskaya I. B. Rozentsveig |
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| Affiliation: | 1.Favorskii Irkutsk Institute of Chemistry, Siberian Division,Russian Academy of Sciences,Irkutsk,Russia |
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| Abstract: | The reaction of N,N-dichlorophenylmethanesulfonamide with trichloroethylene gave a new representative of highly electrophilic N-sulfonyl-substituted polyhalogenated aldehyde imines, phenyl-N-(2,2,2-trichloroethylidene) methanesulfonamide. High reactivity of the product was demonstrated by alkylation of toluene, anisole, thiophene, and 2-chlorothiophene. |
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