Crystal Structure of Binuclear Manganese(Ⅲ) Complex with Schiff-base Ligand,〔Mn_2(C_(22)H_(22)N_2O_2)_2(EtOH)_2 (bipy)〕(ClO_4)_2 |
| |
作者姓名: | FENG Yun-Long LIU Shi-Xiong(Department of Chemistry Fuzhou University Fuzhou 350002) |
| |
作者单位: | Department of Chemistry,Fuzhou University,Fuzhou,350002 |
| |
摘 要: | 1INTRODUCTIONThecoordinationchemistryofmanganeseinthe 2, 3and 4oxidationstatesisreceivingconsiderableattentionduetothebio1ogicalimportanceoftheseions(1i.Anattractivesystemformode1ingthestructureandreactivityofsomemanganoenzymesisbinuclearMn(M)complexescontainingpolydentateSchiffbaseligands.Bothphotochemicalwateroxidationtogeneratedioxygen"'andacid-pro-motedhydrogenperoxideproductiont3ihavebeenreportedforsuchdimer.Wereportherethestructureofthetitlecomplex.2EXPERIMENTAL2.lSynthesisof…
|
关 键 词: | manganese(Ⅲ) complex binuclear complex Schiff base crystal structure |
本文献已被 CNKI 等数据库收录! |