| Crystal Structure of Binuclear Manganese(Ⅲ) Complex with Schiff-base Ligand,〔Mn_2(C_(22)H_(22)N_2O_2)_2(EtOH)_2 (bipy)〕(ClO_4)_2 |
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| 作者姓名： | FENG Yun-Long LIU Shi-Xiong(Department of Chemistry Fuzhou University Fuzhou 350002) |
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| 作者单位： | Department of Chemistry，Fuzhou University，Fuzhou，350002 |
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| 摘 要： | 1INTRODUCTIONThecoordinationchemistryofmanganeseinthe 2, 3and 4oxidationstatesisreceivingconsiderableattentionduetothebio1ogicalimportanceoftheseions(1i.Anattractivesystemformode1ingthestructureandreactivityofsomemanganoenzymesisbinuclearMn(M)complexescontainingpolydentateSchiffbaseligands.Bothphotochemicalwateroxidationtogeneratedioxygen"'andacid-pro-motedhydrogenperoxideproductiont3ihavebeenreportedforsuchdimer.Wereportherethestructureofthetitlecomplex.2EXPERIMENTAL2.lSynthesisof…
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| 关 键 词： | manganese(Ⅲ) complex binuclear complex Schiff base crystal structure |
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