The first metamagnetic thiocyanato-bridged one-dimensional nickel(II) complex |
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Authors: | Chattopadhyay Shouvik Drew Michael G B Diaz Carmen Ghosh Ashutosh |
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Affiliation: | Department of Chemistry, University College of Science, University of Calcutta, 92, A.P.C. Road, Kolkata, 700 009, India. |
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Abstract: | A novel single thiocyanato-bridged one-dimensional polymer, [NiL(NCS)(micro-NCS)]n (L = N1-(1-pyridin-2-yl-ethylidine)propane-1,3-diamine) has been synthesized and characterized by X-ray crystallography and a variable temperature magnetic study; the compound is a metamagnet with a Neél temperature (T(N)) of 3.5 K. |
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