| 2-甲基-3-芳基烯丙基三苯基溴代鏻的合成 |
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| 引用本文： | 高林东,杨尚金,钱旭红. 2-甲基-3-芳基烯丙基三苯基溴代鏻的合成[J]. 合成化学, 1999, 0(1) |
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| 作者姓名： | 高林东 杨尚金 钱旭红 |
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| 作者单位： | 华东理工大学制药工程学院 |
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| 摘 要： | 取代苯甲醛经醇醛缩合、硼氢化还原、溴代反应和成盐反应合成了２-甲基-３-间硝基苯基烯丙基三苯基溴化特和２-甲基-３-对硝基苯基烯丙基三苯基溴化鏻两个化合物，收率分别达８６．４％和６９．０％。结构经ＩＲ，1ＨＮＭＰ确证。
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| 关 键 词： | 醇醛缩合 还原反应 溴代反应 2－甲基－3－对硝基苯基烯丙基三苯基溴化 2-甲基-3-间硝基苯基烯丙基三苯溴化 |
Synthesis of 2 - MethyL-3-aryl-allyltriphenylphosphonium Bromide |
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| GaoLin-Dong, YangShang-Jin, QianXu-Hong. Synthesis of 2 - MethyL-3-aryl-allyltriphenylphosphonium Bromide[J]. Chinese Journal of Synthetic Chemistry, 1999, 0(1) |
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| Authors: | GaoLin-Dong YangShang-Jin QianXu-Hong |
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| Abstract: | Using substituted benzaldehyde as starting materials, 2-methyl-3- (4 - nitrophenyl) allyl-triph- enylphosphonium bromide and 2-methyl-3-(3-nitrophenyl ) allyl-triphenylphosphonium bromide, intermedi-ates of potential antibiotics, were synthesized through Aldol condensation, reduction, bromization, etc.The two compounds, confirmed by IR, 1H NMR, are unreported. |
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| Keywords: | Aldol condensation Reduction Bromization 2-Methyl-3-(4-nitrophenyl ) allyl-triph- enylphosphonium bromide 2-Methyl-3- (3 - nitrophenyl ) al lyl- triphe nylphosphonium bromide. |
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