Formal chemoselective synthesis of leucascandrolide A |
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| Authors: | Ferrié Laurent Reymond Sébastien Capdevielle Patrice Cossy Janine |
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| Affiliation: | Laboratoire de Chimie Organique, ESPCI, CNRS, 10 Rue Vauquelin, 75231 Paris Cedex 05, France. |
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| Abstract: | A chemoselective synthesis of the macrocyclic core of leucascandrolide A has been achieved, utilizing highly enantioselective allylmetalations, an enantioselective Noyori reduction of a propargylic ketone and olefin metatheses as the key steps. |
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