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A study of thin surface layers by multilayer Mössbauer spectroscopy /MMS/
Authors:Cs. Vértes  I. Czakó-Nagy  W. Meisel  M. Kolonits  F. Horkai  A. Vértes
Affiliation:(1) Laboratory of Nuclear Chemistry, L. Eötvös University, P. O. Box 32, H-1518 Budapest, Hungary;(2) Institute of Inorganic and Analytical Chemistry, Johannes Gutenberg University, Mainz, FRG;(3) Structural Chemistry Research Group, L. Eötvös University, P. O. Box 117, H-1431 Budapest, Hungary;(4) Research Laboratory, Budalakk-Paint and Synthetic Rosin Factory, Dunasor 11, H-1044 Budapest, Hungary
Abstract:A stacking Mössbauer technique, MMS has been applied for studying thin surface layers. The surface layers formed on the57Fe film in aqueous solutions of corrosion inhibitors, such as zinc phosphate and barium metaborate, and in distilled water was studied by this method. It has been found that the corrosion is much slower in the presence of zinc phosphate and barium metaborate. XPS analysis suggests the formation of a mixed iron zinc phosphate on the surface of the57Fe film after corrosion in a zinc phosphate solution.
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