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Cu(OAc)2-2,4-lutidine-ZnCl2 as an effective catalyst of functionalization of isobutylene oligomers and 1,2-polybutadiene with methyl diazoacetate |
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| Authors: | Gareev V F Yangirov T A Volodina V P Sultanova R M Biglova R Z Dokichev V A |
| Institution: | 1.Institute of Organic Chemistry, Ufa Scientific Center, Russian Academy of Sciences, Ufa, Bashkortostan, Russia ;2.State Educational Institution of Higher Professional Education, Bashkir State University, Ufa, Bashkortostan, Russia ; |
| Abstract: | The possibility of 1+2]-cycloaddition of methoxycarbonylcarbene generated by catalytic decomposition of methyl diazoacetate in the presence of the Cu(OAc)2-2,4-lutidine-ZnCl2 system to the carbon-carbon double bound in isobutylene oligomers and syndiotactic 1,2-polybutadiene was examined. A comparative analysis of physicochemical properties of the starting compounds and their functionalized products was performed. |
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