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Preferential CO oxidation promoted by the presence of H2 over K-Pt/Al2O3
Authors:Minemura Yuji  Ito Shin-ichi  Miyao Toshihiro  Naito Shuichi  Tomishige Keiichi  Kunimori Kimio
Institution:Institute of Materials Science, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8573, Japan.
Abstract:In preferential CO oxidation in H2-rich gas, K-Pt/Al2O3(K/Pt = 10) was very effective in decreasing CO concentration below 10 ppm in the 375-410 K range, and the turnover frequency of the K-Pt/Al2O3 was 20 times as high as that of Pt/Al2O3 at 353 K; furthermore, the activity of CO oxidation was promoted drastically by the presence of H2.
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