| H2O2—H2SO4体系电化学振荡行为的研究 |
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| 引用本文： | 姚文锐,陈胜.H2O2—H2SO4体系电化学振荡行为的研究[J].化学研究与应用,1999,11(3):287-290. |
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| 作者姓名： | 姚文锐 陈胜 |
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| 作者单位： | 华东冶金学院化工系 |
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| 摘 要： | Ｈ２Ｏ２参与的电化学振荡反应长期以来倍受人们的关注［１，２，３］，文献［１］报道了Ａｇ电极在Ｈ２Ｏ２－ＨＣｌＯ４水溶液中的电势振荡现象；文献［２］报道了Ｐｔ电极Ｈ２Ｏ２－Ｈ２ＳＯ４体系在控电流条件下的电势振荡，其实验的Ｈ２Ｏ２浓度范围为０．０２～０．...
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| 关 键 词： | 电化学振荡 过氧化氢 |
RESEARCH ON ELECTROCHEMICAL OSCILLATION IN H2O2H2SO4 SYSTEM |
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| Yao WenruiChen Sheng.RESEARCH ON ELECTROCHEMICAL OSCILLATION IN H2O2H2SO4 SYSTEM[J].Chemical Research and Application,1999,11(3):287-290. |
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| Authors: | Yao WenruiChen Sheng |
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| Abstract: | The law of potential oscillation of hydrogen peroxide on a platium rotating disk electrode under galvanostatic condition was studied,the concentrations of H2O2 being 070118 mol L-1.On the basis of the experimental results,the mechanism of the oscillation was discussed.It was speculated that the mechanism might be the coupled-type of electrochemical reaction and diffusion controlled. |
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| Keywords: | electrochemical oscillation hydrogen peroxide concentration |
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