| Synthesis of Comblike Poly（methyl methacrylate） by Atom Transfer Radical Polymerization with Poly（ethyl 2-bromoacrylate） as Macroinitiator |
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| 作者姓名： | YanSHI ZhiFengFU YuDongZHANG ShuKeJIAO |
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| 作者单位： | [1]KeyLaboratoryofControlledChemicalReactions,andDepartmentofPolymerEngineering,BeijingUniversityofChemicalTechnology,Beijing100029 [2]PolyolefinNationalEngineeringResearchCenter,BeijingResearchInstituteofChemicalIndustry,Beijing100013 |
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| 摘 要： | Comblike poly(methyl methacrylate) was synthesized by atom transfer radical polymerization of methyl methacrylate with poly(ethyl 2-bromoacrylate) as a macroinitiator, which was prepared by conventional free radical polymerization of ethyl 2-bromoacrylate. The obtained comblike polymers were characterized by GPC and ^1H NMR.
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| 关 键 词： | 合成 冠状聚合物 聚（甲基丙烯酸脂） 原子迁移 自由基聚合 乙基-2-溴代丙烯酸脂 |
Synthesis of Comblike Poly(methyl methacrylate) by Atom Transfer Radical Polymerization with Poly(ethyl 2-bromoacrylate) as Macroinitiator |
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| YanSHI ZhiFengFU YuDongZHANG ShuKeJIAO.Synthesis of Comblike Poly(methyl methacrylate) by Atom Transfer Radical Polymerization with Poly(ethyl 2-bromoacrylate) as Macroinitiator[J].Chinese Chemical Letters,2003,14(12):1289-1292. |
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| Authors: | Yan SHI Zhi Feng FU Yu Dong ZHANG Shu Ke JIAO |
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| Abstract: | Comblike poly(methyl methacrylate) was synthesized by atom transfer radical polymerization of methyl methacrylate with poly(ethyl 2-bromoacrylate) as a macroinitiator, which was prepared by conventional free radical polymerization of ethyl 2-bromoacrylate. The obtained comblike polymers were characterized by GPC and 1H NMR. |
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| Keywords: | Comblike polymer atom transfer radical polymerization (ATRP) macroinitiator poly(methyl methacrylate) ethyl 2-bromoacrylate |
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