Synthesis and characterization of rhenium(VII) oxide complexes of phenothiazines |
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| Authors: | Netkal M. Made Gowda Hnin P. Phyu Brian E. Ackerson |
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| Affiliation: | (1) Department of Chemistry, Western Illinois University, 61455 Macomb, IL, USA |
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| Abstract: | Summary Five complexes of rhenium(VII) oxide with N-alkylphenothiazines have been synthesized and characterized on the basis of elemental analyses, molar conductances, and u.v.-vis., i.r. and n.m.r. spectral data. The molecular formulas of the new ionic complexes are: [ReO3(PTZ)2(H2O)][ReO4], PTZ = chlorpromazine, promethazine or ethopropazine; [ReO3(TF)(H2O)][ReO4], TF = trifluoperazine; and [ReO3(TR)3][ReO4(H2O)2]·H2O, TR = thioridazine. Tentative structures have been proposed. |
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