Über Chalkogenolate. 123. Untersuchungen über N-Cyanomonothiocarbimidsäure. 3. O,S-Dimethylester der N-Cyanomonothiocarbimidsäure. Thiolyse und Hydrolyse des Esters |
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Authors: | H. Hlawatschek G. Gattow |
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Abstract: | On Chalcogenolates. 123. Studies on N-Cyanomonothiocarbimic Acid. 3. O, S-Dimethyl Ester of N-Cyanomonothiocarbimic Acid. Thiolysis and Hydrolysis of this Ester (H3CO)(H3CS)C?N? CN has been prepared by reaction of K2[SOC?N? CN] · H2O with H3CI. The thiolysis of this ester gives (H3CO)(H3CS)C?N? CS? NH2. The acid hydrolysis forms (H3CO)(H3CS)C?N? CO? NH2 via [(H3CO)(H3CS)C?N? C?NH]Cl. All compounds have been characterized by diverse methods. |
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