Etude de la réaction de l'acétylacétone avec les diamines hétéroaromatiques

The inluence of the starting o-diamine on the reaction products is shown in the condensation of heteroaromatic o-diamines with acetylacetone; 2,3- and 3,4-diaminopyridines gave only a crotonic intermediate providing imidazopyridines. On the other hand, 1,5-diaminoimidazoles gave tow types of compounds, imidazotriazepines and imidazopyridines. Triazolopyridazines were formed from 3,4-diaminotriazoles.