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N-chlorination of nylon fabric and polyurea-6
Authors:A A Koutinas  P G Demertzis
Abstract:In this article the preparation of N-chloro Nylon fabric, with Nylon-66 as weft and Nylon-6 as warp is described. The N-chlorination of this fabric was achieved by using tertiary butyl hypochlorite in carbon tetrachloride as the chlorinating agent. The percentage of N-chlorinated amide groups in the fabric obtained was 30.6. Methods of preparation of N-chloro polyurea-6 are also reported. The N-chlorination of these compounds was acheived in a heterogenious medium. N-chloro polyurea-6 was prepared by reacting it with tert-butyl hypochlorite. In Polyuera-6 the percentage of N-chlorination was equal to 100. The 100% N-chlorinated polyurea-6 did not give? NH? bands at 3.05 and 6.50 μ in the infrared spectra.
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