Synthesis and thermal analysis of some oligomeric silicon derivatives of ferrocene

This article reports a study of the catalytic addition reaction of ferrocene containing dihydrosilane to diacetylenic silicon derivatives. A hypothetical structure based on reaction kinetics and spectral data is presented. The oligomers obtained were studied by TG and DTA from ambient temperature to 1000°C in oxygen atmosphere (80 mL/min). The existance of phenyl groups in the structure of the oligomers makes them less stable than those with derivatives.