Synthesen und chemische Reaktionen neuer Chinonderivate mit 1,6-Methano[10]annulenpartialstruktur oder ihrer Valenztautomeren |
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Authors: | Richard Neidlein Christoph Martin Radke |
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Abstract: | Syntheses and Chemical Reactions of New Quinone Derivatives with 1,6-Methano10]annulene Fragments or their Valencetautomers The coupling of 2-Methoxy-1,6-methano10]annulene with aryldiazonium salts leads to the corresponding quinone hydrazones. These compounds undergo reduction with LiAlH4, condensation with hydrazines and hydrazides and alkylation at the carbonyl O-atom or the hydrazone N-atom. |
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