Thermisch beständige Trialkyl-2,2,2-trifluor-1-(trifluormethyl)-ethoxy-phosphonium Iodide |
| |
| Authors: | D Dakternieks G-V Rschenthaler |
| |
| Institution: | D. Dakternieks,G.-V. Röschenthaler |
| |
| Abstract: | Thermally Stable Trialkyl-2,2,2-trifluoro-1-(trifluoromethyl)-ethoxyphosphonium Iodides The phosphinites R1R2POCH(CF3)2 (R1 = R2 = Me, tBu; R1 = Me, R2 = tBu) react with methyl iodide to give the thermally very stable phosphonium iodides R1R2MePOCH(CF3)2]+I?. In the case of tBu2POCH(CF3)2 a sublimable 1:1 adduct is formed with boron trichloride. |
| |
| Keywords: | |
|
|
