Abstract: | The structural changes in the potassium graphitide KC24 in its interaction with ?-caprolactone, γ-butyrolactone and pivalolactone are examined by profilometric measurement and electron scanning microscopy. The interaction of KC24 with a nonpolymerizable lactone-γ-butyrolactone proceeds without delamination of the graphitide. The polymerization of ?-caprolactone and pivalactone in the interlayer spaces of KC24 leads to destruction of the initiators structure. An increase in the temperature and monomer concentration enhances the delamination of the graphitide. |