Annulation of benzamides with [60]fullerene through palladium(II)-catalyzed C-H bond activation |
| |
| Authors: | Chuang Shih-Ching Rajeshkumar Venkatachalam Cheng Chun-An Deng Jie-Cheng Wang Guan-Wu |
| |
| Affiliation: | Department of Applied Chemistry, National Chiao Tung University, Hsinchu, Taiwan, ROC 30010. jscchuang@faculty.nctu.edu.tw |
| |
| Abstract: | Palladium-catalyzed heteroannulation of N-substituted benzamides with [60]fullerene, which proceeds through direct sp(2) C-H bond activation to form 7-membered ring pallada-intermediate with C(60), led to formation of [60]fulleroisoquinolinones in moderate to good yields (8-64% based on recovered C(60)). A plausible reaction pathway is proposed. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
|
