Surprising coordination for plutonium in the first plutonium(III) borate |
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| Authors: | Wang Shuao Alekseev Evgeny V Depmeier Wulf Albrecht-Schmitt Thomas E |
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| Institution: | Department of Civil Engineering and Geological Sciences, 156 Fitzpatrick Hall, University of Notre Dame, Notre Dame, Indiana 46556, United States. |
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| Abstract: | The first plutonium(III) borate, Pu(2)B(12)O(18)(OH)(4)Br(2)(H(2)O)(3)]·0.5H(2)O, has been prepared by reacting plutonium(III) with molten boric acid under strictly anaerobic conditions. This compound contains a three-dimensional polyborate network with triangular holes that house the plutonium(III) sites. The plutonium sites in this compound are 9- and 10-coordinate and display atypical geometries. |
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