Unexpected conversion of a hexacyanometallate to a homoleptic nitrile complex with triphenylborane substituents |
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| Authors: | Schelter Eric J Shatruk Mikhail Heintz Robert A Galán-Mascarós José Ramón Dunbar Kim R |
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| Affiliation: | Department of Chemistry, Texas A&M University, P.O. Box 30012, College Station, TX 77842-3012, USA. dunbar@mail.chem.tamu.edu. |
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| Abstract: | The homoleptic, triphenylborane adduct of the hexacyanochromate anion was structurally characterized and found to be a product in which all six cyanide ligands have undergone isomerization to nitrile groups. |
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