Coordination of pertechnetate [TcO4]- to actinides |
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| Authors: | Sarsfield Mark J Sutton Andrew D May Iain John Gordon H Sharrad Clint Helliwell Madeleine |
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| Affiliation: | Centre for Radiochemistry Research, Department of Chemistry, The University of Manchester, Manchester, UK M13 9PL. mark.j.sarsfield@man.ac.uk. |
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| Abstract: | The ability of [TcO(4)](-) to coordinate directly to tetra- and hexa-valent actinides in the presence of organic P[double bond, length as m-dash]O ligands is confirmed in the crystallographically characterised complexes [UO(2)(TcO(4))(2)(Ph(3)PO)(3)] and [Th(TcO(4))(4)((n)Bu(3)PO)(4)]. |
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