Regioselective oxyalkylation of vinylarenes catalyzed by diatomite-supported manganese oxide nanoparticles |
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| Authors: | Sun Huayin Zhang Yonghui Guo Fengfeng Zha Zhenggen Wang Zhiyong |
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| Institution: | Hefei National Laboratory for Physical Sciences at Microscale, CAS Key Laboratory of Soft Matter Chemistry and Department of Chemistry, University of Science and Technology of China, Hefei, 230026, PR China. |
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| Abstract: | A regioselective oxyalkylation reaction of vinylarenes with cyclic ethers was developed under the catalysis of a new heterogeneous catalyst, the diatomite-supported Mn(3)O(4) nanoparticles (SMONP-1). The use of this heterogeneous catalyst provided a novel approach for the synthesis of α-carbonyled β-alkylated aryl derivatives via a sp(3) C-H bond functionalization under mild aerobic conditions. |
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