Abstract: | We consider the problem of the rectified current induced by laser radiation in the STM junction when the tip is placed above a small molecule like CO or NO. This is calculated assuming a simple tight-binding model for the tunneling junction including the adsorbate and using nonequilibrium Green's functions techniques. The coupling between tunneling electrons and the molecule vibrational modes is taken into account by a local electron-phonon interaction term. In a second step we estimate the excitation rate of the molecule vibrations for a given laser power. This value is then used to obtain the relative change in the rectified current when the laser is in resonance with a molecule vibration. For a moderate laser power of 2 kW/cm2 a relative change of 1 to 3% is predicted. |