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Spin-spin coupling of77Se and31P nuclei in cyclic organophosphorous compounds
Authors:T. A. Zyablikova  A. V. Il'yasov  S. N. Ignat'eva  S. F. Malatsion  O. A. Erastov
Affiliation:(1) A. E. Arbuzov Institute of Organic and Physical Chemistry, USSR;(2) Academy of Sciences of the USSR, Kazan Filiate
Abstract:We have established that direct phosphorus-selenium spin-spin coupling constants in cyclic compounds with P=Se exocyclic and P-C endocyclic bonds are found in the range1JPSe=–708 to –859 Hz; in this case, it is greater for the axial orientation of P=Se than for the equatorial orientation.Deceased.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 4, pp. 776–780, April, 1990.
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