| A study on some macrocyclic bicopper(Ⅱ) complexes as the model compounds of superoxide dismutase |
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| 作者姓名： | QIAN Wen MEI Guang-Quan LUO Qin-HuiState Key Laboratory of Coordination Chemistry Coordination Chemistry Institute Nanjing University Nanjing Jiangsu China |
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| 作者单位： | QIAN，Wen MEI，Guang-Quan LUO，Qin-HuiState Key Laboratory of Coordination Chemistry，Coordination Chemistry Institute，Nanjing University，Nanjing，Jiangsu 210093，China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China. |
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| 摘 要： | 24-Membered macrocyclic bicopper(Ⅱ) complexes wth bridging ligand imidzao-late,SCN-,N3-and H2O respectively were synthesized by condensation of diacetylpyridine with 3-oxapentane-1,5-diamine.As the model compounds of superoxide dismutase (SOD),the relationship between their SOD activities and properties of bridging ligands and redox potentials of copper(Ⅱ) were studied.
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| 关 键 词： | Macrocyclic complex bicopper(Ⅱ) superoxide dismutase (SOD) model compound activity redox potential |
A study on some macrocyclic bicopper(II) complexes as the model compounds of superoxide dismutase |
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| QIAN,Wen MEI,Guang-Quan LUO,Qin-HuiState Key Laboratory of Coordination Chemistry,Coordination Chemistry Institute,Nanjing University,Nanjing,Jiangsu ,China.A study on some macrocyclic bicopper(II) complexes as the model compounds of superoxide dismutase[J].Chinese Journal of Chemistry,1996,14(2):114-122. |
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| Authors: | QIAN Wen MEI Guang-Quan LUO Qin-HuiState Key Laboratory of Coordination Chemistry Coordination Chemistry Institute Nanjing University Nanjing Jiangsu China |
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| Institution: | QIAN,Wen MEI,Guang-Quan LUO,Qin-HuiState Key Laboratory of Coordination Chemistry,Coordination Chemistry Institute,Nanjing University,Nanjing,Jiangsu 210093,China |
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| Abstract: | 24-Membered macrocyclic bicopper(II) complexes wth bridging ligand imidzaolate, SCN?, N3? and H2O respectively were synthesized by condensation of diacetylpyridine with 3-oxapentane-1,5-diamine. As the model compounds of superoxide dismutase (SOD), the relationship between their SOD activities and properties of bridging ligands and redox potentials of copper(II) were studied. |
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| Keywords: | Macrocyclic complex bicopper(II) superoxide dismutase (SOD) model compound activity redox potential |
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