An oxidative carbon-carbon bond formation system in cycloalkane-based thermomorphic multiphase solution |
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| Authors: | Kim Shokaku Noda Satoko Hayashi Kanako Chiba Kazuhiro |
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| Affiliation: | Laboratory of Bio-organic Chemistry, Tokyo University of Agriculture and Technology, Tokyo, Japan. |
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| Abstract: | A selective anodic oxidation system in which a carbocation intermediate is generated exclusively by use of a temperature-controlled multiphase solution to separate the different stages of the reaction from each other and from the products is described. The formation of a thermomorphic middle layer in an electrolytic solution composed of c-Hex and LPC/MeNO2 results in enhanced interaction between aliphatic alkenes and polar unstable cation. |
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