Specific features of the structure of germanium(IV) complexes with polybasic acids |
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Authors: | V S Sergienko L Kh Minacheva A V Churakov |
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Institution: | 1.Kurnakov Institute of General and Inorganic Chemistry,Russian Academy of Sciences,Moscow,Russia |
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Abstract: | The specific features revealed in the structure of germanium(IV) compounds with ligands in the form of anions of polybasic
acids (monoamine, diamine, and triamine complexones, i.e., hydroxyethylidene-diphosphonic and carboxylic acids) have been
considered. The influence of the individuality of specific acids on the structure type (mononuclear, binuclear, trinuclear,
hexanuclear, polynuclear), the coordination mode of monodentate ligands and donor atoms of polydentate ligands (terminal,
bridging, chelating, chelating-bridging), and variants of the coordination of polydentate ligands, i.e., anions of polybasic
acids, with metal atoms (germanium, rare-earth elements, copper, barium), as well as on the dependence of the Ge-O bond length
on the individual nature of ligands (OH, H2O, O(oxo)) and donor atoms of polydentate ligands α- and β-O(carb), O(hydr), O(P)] and their function in the structure (terminal,
bridging, chelating, chelating-bridging), has been analyzed using 28 homometallic and heterometallic complexes as an example. |
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